Long Term Monitoring / Temporally Integrated Monitoring of Ecosystems

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Long Term Monitoring Project (LTM)
Temporally Integrated Monitoring of Ecosystems (TIME)
LTM Sampling Regions and Cooperators
TIME Sampling Regions and Cooperators
Trends in Water Quality

Long Term Monitoring Project (LTM)

The LTM monitoring program tracks the status of acidified and acid-sensitive lakes and streams. This program measures critical chemical variables which provide insights into many measures of aquatic ecosystem health. The LTM program is used to better understand long-term trends in acidification and recovery in the Northeastern and Mid-Atlantic United States. The LTM program is operated with numerous collaborators in state agencies, academic institutions and other federal agencies.

The primary objective of the LTM program is to detect long-term trends in acid/base status of lakes and streams across a gradient of acidic deposition. LTM consists of a site network of lakes and streams that are particularly sensitive to acidity due in part to their underlying geology. Most site records date back to the mid-1980s or earlier. Sites are sampled 3 to 15 times per year with a higher proportion of sampling conducted in the spring to coincide with higher rates of runoff (e.g., snow melt) and higher stream flows because the aquatic effects of acidic deposition often exhibit seasonality (e.g., causing harm in the winter or spring when the more sensitive life stages of some fish species are present). LTM water chemistry data are used to characterize how the most sensitive aquatic systems in each region are responding to changing acid deposition, as well as providing information on seasonal chemistry and episodic acidification.

Temporally Integrated Monitoring of Ecosystems (TIME)

TIME was a companion project to LTM that was developed as a "special" study within EPA's Environmental Monitoring and Assessment Program (EMAP)-Surface Waters to track long term trends in the acid-relevant chemistry of specific classes of acid-sensitive lakes and streams. The TIME monitoring program consisted of probability surveys designed to answer questions like: “how many acidic lakes are there?" and "what is the trend in the number or proportion of lakes which are acidic?” These questions can be answered for specific types of lakes (e.g., seepage vs. drainage lakes) or for specific regions (e.g., Adirondacks vs. New England uplands). TIME was statistically based, thereby allowing regional population estimates of acid sensitivity status to be developed. TIME consisted of a synoptic survey of 74 acid-sensitive lakes in the Northeast and a separate synoptic survey of 58 acid-sensitive streams in the Mid-Atlantic. Waters were sampled annually in the late summer (lakes) and spring (streams) and the regional estimates they generated were specific to that time period. Sampling of this special study ended in 2015 for streams in the mid-Atlantic and 2016 for lakes in the Northeast with the realization of the program goals. The water quality and other environmental data are available on request.

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LTM Sampling Regions and Cooperators

Adirondack Mountains

Participation —sample collection and laboratory analysis for seasonal or monthly samples from 52 LTM lakes in the Adirondack Mountains of New York
Cooperators — Paul Smith’s College Adirondack Watershed Institute, Adirondack Lake Survey Corporation, New York State Energy Research and Development Authority, New York State Department of Environmental Conservation, and US Geological Survey District Office in Troy, NY
Period of Record — mid 1980s through present

New England

Vermont

Participation — sampling and laboratory analysis during spring runoff on 7 lake outlets and open water sampling during the spring, summer and fall from 12 LTM lakes
Cooperator — Vermont Department of Environmental Conservation
Period of Record — 1983 through present

Maine

Participation — sample collection and laboratory analysis for quarterly samples from 15 Maine LTM lakes
Cooperators —US Geological Survey, University of New Hampshire , and University of Maine
Period of Record — 1982 through present

Northern Appalachian Plateau

Catskill Mountains, NY

Participation — sample collection, laboratory analysis and stream gauging for monthly samples from 4 Catskill Mountain streams
Cooperator — US Geological Survey New York Water Center
Period of Record — 1983 through present

Central Appalachians

Virginia

Participation — sample collection and laboratory analysis for weekly samples at four sites, seasonal samples at 72 sites, sample collection every two hours during episodic high-flow conditions at three sites with continuous discharge gauging in Virginia streams
Cooperators —National Park Service, University of Virginia
Period of Record — 1979 through present

Pennsylvania

Participation — sample collection, laboratory analysis and stream gauging for monthly samples from 5 headwater Pennsylvania streams. Sampling was discontinued in 2013
Cooperators —US Geological Survey, Pennsylvania State University
Period of Record — 1988 through 2013

TIME Sampling Regions and Cooperators

Participation

Lake sample collection and laboratory analysis for 74 annual TIME waters in New York, Maine, New Hampshire, Vermont, Massachusetts and Rhode Island. Stream samples collection and laboratory analysis for 56 annual TIME waters in Virginia, West Virginia, Maryland, and Pennsylvania. Sampling was discontinued in 2016 for lakes and 2015 for streams.

Cooperators

For lakes, cooperators included Adirondack Lake Survey Corporation, New York State Energy Research and Development Authority, New York State Department of Environmental Conservation, US Geological Survey District Office in Troy, NY , University of New Hampshire, and University of Maine. For streams, cooperators include National Park Service, University of Virginia, US Geological Survey, Pennsylvania State University

Trends in Water Quality

The LTM network provides information on the chemistry of lakes and streams to indicate how water bodies are responding to changes in SO₂ and NO_x emissions.

Regional Trends in Sulfate, Nitrate, Acid Neutralizing Capacity (ANC), Base Cations, and Dissolved Organic Carbon (DOC) at Long Term Monitoring Sites, 1990–2019
Region	Water Bodies Covered	% of Sites with Improving Sulfate Trend	% of Sites with Improving Nitrate Trend	% of Sites with Improving ANC Trend	% of Sites with Improving Base Cations Trend
Adirondack Mountains	58 lakes in NY*	99%	76%	79%	93%
New England	26 lakes in ME and VT	100%	15%	74%	64%
Catskills/N. Appalachian Plateau	9 streams in NY and PA**	80%	43%	70%	90%
Central Appalachians	70 streams in VA	54%	79%	11%	41%

Notes:

Trends are determined by multivariate Mann-Kendall tests
Trends are significant at the 95 percent confidence interval (p < 0.05)
Sum of Base Cations calculated as (Ca+Mg+K+Na)

* Data for Adirondack lakes from 1992
** Data for PA streams in N. Appalachian Plateau is only through 2015

Source: EPA, 2020

This table shows regional trends in acidification from 1990 (before implementation of the Acid Rain Program) to 2019 in lakes and streams throughout the LTM program. Acidified drainage water mobilizes toxic forms of aluminum from soils and clays, harming fish and wildlife. Five chemical indicators of aquatic ecosystem response to emission changes are presented: trends in sulfate and nitrate anions, acid neutralizing capacity (ANC), and base cations. These indicators provide information regarding the surface water sensitivity to acidification and the degree of impact on the aquatic ecosystem. Trends in these measured chemical indicators in drainage waters allow for the determination of whether the water bodies are improving and heading towards recovery or if they are still acidifying. The following is a description of each indicator represented in the table:

Sulfate is the primary anion in most acid-sensitive waters and has the potential to acidify drainage waters and leach base cations and toxic forms of aluminum from the soils.

Nitrate has the same potential as sulfate to acidify drainage waters. However, nitrogen is an important nutrient for plant growth and a large portion of nitrogen inputs from deposition are quickly incorporated into plants as organic nitrogen, leaving less leaching of nitrate into surface waters. Water nitrate concentrations are often variable and reductions in nitrogen deposition are slow to be reflected in long term trends.

Acid Neutralizing Capacity (ANC) is a measure of overall buffering capacity against acidification, and indicates the ability to neutralize strong acids that enter aquatic systems. When ANC is low, and especially when it is negative, stream water pH is also low (less than pH 6, commonly less than pH 5), and may be harmful to fish and other aquatic organisms essential for a healthy aquatic ecosystem. Recovery of an aquatic ecosystem is indicated by increasing trends in ANC and base cations and decreasing trends in sulfate and nitrate concentrations.

Base cations is the sum of the positively charged calcium, magnesium, sodium and potassium ions in soils and surface waters that buffer both sulfate and nitrate anions, thereby preventing surface water acidification. Base cation availability is largely a function of underlying geology and soil age, such that young soils of cation-rich bedrock will tend to have a greater buffering capacity.