PES-51

TECHNICAL PRODUCT BULLETIN #M-12
USEPA, OEM REGULATIONS IMPLEMENTATION DIVISION
ORIGINAL LISTING DATE: AUGUST 31, 1992
REVISED LISTING DATE: SEPTEMBER 13, 1995
"PES-51"

I. NAME, BRAND, OR TRADEMARK
PES-51 Type of Product: Miscellaneous Oil Spill Control Agent

II. NAME, ADDRESS, AND TELEPHONE NUMBER OF MANUFACTURER/CONTACT
Practical Environmental Solutions (formerly known as Petroleum Environmental Services) P.O. Box 12563 San Antonio, Texas 78212 Phone: (210) 493-7172 Mobile Phone: (210) 875-4011 Fax: (210) 493-7172 Email: [email protected] Website: www.pes51.com (Mr. Bill Sims)

III. NAME, ADDRESS, AND TELEPHONE NUMBER OF PRIMARY DISTRIBUTORS
Practical Environmental Solutions (formerly known as Petroleum Environmental Services) P.O. Box 12563 San Antonio, Texas 78212 Phone: (210) 493-7172 Mobile Phone: (210) 875-4011 Fax: (210) 493-7172 Email: [email protected] Website: www.pes51.com (Mr. Bill Sims)

IV. SPECIAL HANDLING AND WORKER PRECAUTIONS FOR STORAGE AND FIELD APPLICATION
1. Flammability: 124ºF 2. Ventilation: Handle product in a normal well ventilated place. 3. Skin and eye contact; protective clothing; treatment in case of contact: Although PES-51 is expected not to pose any specific health hazard, the following precautions are recommended due to possible irritation from the biological by-products contained in the product. Avoid contact with skin, eyes, and clothing. Avoid prolonged or repeated contact with skin, breathing mist, and do not take internally. Keep product away from heat, sparks, and flames, and store in a cool, dry, well ventilated place, away from incompatible materials. Vent container in warm weather to relieve pressure. Do not cut, grind, weld or drill on or near product containers. Handle empty containers just as would the full ones. 4.a. Maximum storage temperature: NA 4.b. Minimum storage temperature: NA 4.c. Optimum storage temperature range: NA 4.d. Temperatures of phase separations and chemical changes: Not applicable, but PES-51 freezes at -142ºF.

IV. SPECIAL HANDLING AND WORKER PRECAUTIONS FOR STORAGE AND FIELD APPLICATION

1. Flammability:
124ºF
2. Ventilation:
Handle product in a normal well ventilated place.
3. Skin and eye contact; protective clothing; treatment in case of contact:
Although PES-51 is expected not to pose any specific health hazard, the following precautions are recommended due to possible irritation from the biological by-products contained in the product. Avoid contact with skin, eyes, and clothing. Avoid prolonged or repeated contact with skin, breathing mist, and do not take internally. Keep product away from heat, sparks, and flames, and store in a cool, dry, well ventilated place, away from incompatible materials. Vent container in warm weather to relieve pressure. Do not cut, grind, weld or drill on or near product containers. Handle empty containers just as would the full ones.
4.a. Maximum storage temperature: NA
4.b. Minimum storage temperature: NA
4.c. Optimum storage temperature range: NA
4.d. Temperatures of phase separations and chemical changes: Not applicable, but PES-51 freezes at -142ºF.

V. SHELF LIFE
6 years (unopened drum), 1 year (opened drum).

VI. RECOMMENDED APPLICATION PROCEDURE
1. Application Method: The following PES-51 application methods are applicable for the full range of PES-51 industrial uses, including shoreline and surface treatment, tank cleaning and equipment decontamination. The selection of the method(s) will be dependent on the level and extent of hydrocarbon contamination, type of oil, and its degree of weathering/emulsion and the nature and type of surface to be treated or cleaned. Equipment availability, logistics and manpower requirements should also be considered. Application methods may be combined, if necessary. In addition, for shoreline cleaning, the treatment area will be boomed and contained prior to PES-51 usage. For equipment decontamination, the use of portable de-con pools or secondary containment liners are recommended. PORTABLE EQUIPMENT Hand Held Spraying - Spray PES-51 on the contaminated area using a Chapin Steel Sprayer #1729 (or equivalent), 2.5 gallons capacity, or the AU 8000 MicroNair sprayer. After application, allow 3 to 5 minutes for soaking without allowing evaporation of PES-51 (weather dependent). When saturation is attained, hydrocarbon will be seen running off the impacted surface. Rinse the treated surface with available water (fresh or sea water) from the pump until no hydrocarbon remains. The water should be used at ambient temperature. Depending on level and extent of contamination, a pressure washer may also be used for rinsing (ambient may be used). Collect the effluent hydrocarbons with absorbent booms and pads, and squeeze off the oil contaminants from the booms and pads for reuse as process oil. Airless Sprayer - Depending on the level and extent of the hydrocarbon contamination and the nature of the impacted surface, an airless type sprayer may be used for direct product application. Common types of airless sprayers are: Airlessco, Graeco or equivalents. These airless sprayers can have single or multi-hose attachments and can include wand extensions as required. Application rate and pressure will vary depending on the equipment type and site specific conditions. After spraying with PES-51, allow to soak for 3 to 5 minutes (weather dependent) avoiding evaporation, rinse/flush surfaces with pumps, fire hoses, deluge headers or pressure washers (ambient). Pressure Washer with Syphon Feed System - Depending on the level and extent of the hydrocarbon contamination and the nature of the impacted surface proposed for treatment, a pressure washer may be used for direct product application. In most applications, hot water (greater than 120ºF) is not necessary. Common types of pressure washers are: Hotsy and Lambda, or equivalents. These pressure washers have a variable rate "detergent syphon feed" system for PES-51 application and can have single or multi-hose attachments which can include wand extensions. Application rate and pressure will vary depending on equipment type and site specific conditions. After spraying with PES-51, allow to soak for 3 to 5 minutes (weather dependent) avoiding evaporation, rinse/flush surfaces with pumps, fire hoses, deluge headers or pressure washers (ambient). Air Knife (Modified for PES-51 Application) - PES has developed a patent-pending modified air knife system for product application. This method was developed primarily for rocky, cobble, bedrock type shorelines with both surface subsurface oil. The modified air knife delivers the PES-51 in both a liquid stream (125 psi) or as an aerosol. Compressed air is used to dilate subsurface sediments and allow for distribution of the PES-51. The air knife method is also applicable for surface treatment of impacted rocks, bulkheads, seawalls, rip-rap jetties, etc. After spraying with PES-51, allow to soak for 3 to 5 minutes (weather dependent) avoiding evaporation, rinse/flush surfaces with pumps, fire hoses, deluge headers or pressure washers (ambient). For subsurface treatment, continue flushing with large quantities of low-pressure seawater at ambient temperatures. MOBILE EQUIPMENT Boat Spraying - The recommended application rate is 1 to 5 gallons per 200 sq. ft., from a boat with speed of 1 to 3 knots, depending on the sea conditions and oil film thickness on the rocks. For a boat with a mounted AU-8110 MicroNair sprayer (or equivalent sprayer) and a spray swath of about 20 feet, travelling at approximately two knots, 25 acres/hr will be treated. After spraying, rinse PES-51 off the rocks with a hard, coarse spray of sea water. Standard size pumps with fire hoses or deluge headers may be used. Higher pressure rinses may be required if oil is thick and weathered. The shoreline may also be sprayed from the beach side, which will force the oil into the containment boom. Helicopter Deployed Spraying - Aerial spraying can be utilized for shore treatments and pretreatment with the AU 5000 atomizer (MicroNair) or equivalent sprayer. The recommended aerial application of PES-51 is 14 to 23 liters/minute. The AU 5000 (or equivalent) can be used with fixed-wing aircraft and helicopters operating at speeds of 90 MPH (145 Km/Hr) and more. The smaller AU 7000 sprayer (or equivalent) is recommended for use at airspeeds below 90 MPH. After spraying, the hydrocarbons can be rinsed off the shore rocks as described above with hand held pumps, deluge headers or boat spraying. Vehicular Spraying - The recommended vehicular spraying is 50 to 150 ft2/gallon depending on climatic conditions. A MicroNair vehicle-mounted sprayer is recommended. This unit is a self contained sprayer kit that combines the AU 8000 sprayhead (or equivalent) with a powerful 4-stroke engine and a 60 liter chemical tank to give complete product coverage. After spraying, the hydrocarbons can then be rinsed off the shore rocks as described above with hand held pumps, deluge headers or boat spraying. 2. Concentration/Application Rate: The product comes already mixed, and ready for use. For specific application, see rate of application as indicated above. 3. Conditions for Use: Water temperature and salinity do not effect the product performance. PES-51 is effective against hydrocarbons only, and the age of the hydrocarbon is not relevant.

VI. RECOMMENDED APPLICATION PROCEDURE

1. Application Method:
The following PES-51 application methods are applicable for the full range of PES-51 industrial uses, including shoreline and surface treatment, tank cleaning and equipment decontamination. The selection of the method(s) will be dependent on the level and extent of hydrocarbon contamination, type of oil, and its degree of weathering/emulsion and the nature and type of surface to be treated or cleaned. Equipment availability, logistics and manpower requirements should also be considered. Application methods may be combined, if necessary. In addition, for shoreline cleaning, the treatment area will be boomed and contained prior to PES-51 usage. For equipment decontamination, the use of portable de-con pools or secondary containment liners are recommended.
PORTABLE EQUIPMENT
Hand Held Spraying - Spray PES-51 on the contaminated area using a Chapin Steel Sprayer #1729 (or equivalent), 2.5 gallons capacity, or the AU 8000 MicroNair sprayer. After application, allow 3 to 5 minutes for soaking without allowing evaporation of PES-51 (weather dependent). When saturation is attained, hydrocarbon will be seen running off the impacted surface. Rinse the treated surface with available water (fresh or sea water) from the pump until no hydrocarbon remains. The water should be used at ambient temperature. Depending on level and extent of contamination, a pressure washer may also be used for rinsing (ambient may be used). Collect the effluent hydrocarbons with absorbent booms and pads, and squeeze off the oil contaminants from the booms and pads for reuse as process oil.
Airless Sprayer - Depending on the level and extent of the hydrocarbon contamination and the nature of the impacted surface, an airless type sprayer may be used for direct product application. Common types of airless sprayers are: Airlessco, Graeco or equivalents. These airless sprayers can have single or multi-hose attachments and can include wand extensions as required. Application rate and pressure will vary depending on the equipment type and site specific conditions. After spraying with PES-51, allow to soak for 3 to 5 minutes (weather dependent) avoiding evaporation, rinse/flush surfaces with pumps, fire hoses, deluge headers or pressure washers (ambient).
Pressure Washer with Syphon Feed System - Depending on the level and extent of the hydrocarbon contamination and the nature of the impacted surface proposed for treatment, a pressure washer may be used for direct product application. In most applications, hot water (greater than 120ºF) is not necessary. Common types of pressure washers are: Hotsy and Lambda, or equivalents. These pressure washers have a variable rate "detergent syphon feed" system for PES-51 application and can have single or multi-hose attachments which can include wand extensions. Application rate and pressure will vary depending on equipment type and site specific conditions. After spraying with PES-51, allow to soak for 3 to 5 minutes (weather dependent) avoiding evaporation, rinse/flush surfaces with pumps, fire hoses, deluge headers or pressure washers (ambient).
Air Knife (Modified for PES-51 Application) - PES has developed a patent-pending modified air knife system for product application. This method was developed primarily for rocky, cobble, bedrock type shorelines with both surface subsurface oil. The modified air knife delivers the PES-51 in both a liquid stream (125 psi) or as an aerosol. Compressed air is used to dilate subsurface sediments and allow for distribution of the PES-51. The air knife method is also applicable for surface treatment of impacted rocks, bulkheads, seawalls, rip-rap jetties, etc. After spraying with PES-51, allow to soak for 3 to 5 minutes (weather dependent) avoiding evaporation, rinse/flush surfaces with pumps, fire hoses, deluge headers or pressure washers (ambient). For subsurface treatment, continue flushing with large quantities of low-pressure seawater at ambient temperatures.
MOBILE EQUIPMENT
Boat Spraying - The recommended application rate is 1 to 5 gallons per 200 sq. ft., from a boat with speed of 1 to 3 knots, depending on the sea conditions and oil film thickness on the rocks. For a boat with a mounted AU-8110 MicroNair sprayer (or equivalent sprayer) and a spray swath of about 20 feet, travelling at approximately two knots, 25 acres/hr will be treated. After spraying, rinse PES-51 off the rocks with a hard, coarse spray of sea water. Standard size pumps with fire hoses or deluge headers may be used. Higher pressure rinses may be required if oil is thick and weathered. The shoreline may also be sprayed from the beach side, which will force the oil into the containment boom.
Helicopter Deployed Spraying - Aerial spraying can be utilized for shore treatments and pretreatment with the AU 5000 atomizer (MicroNair) or equivalent sprayer. The recommended aerial application of PES-51 is 14 to 23 liters/minute. The AU 5000 (or equivalent) can be used with fixed-wing aircraft and helicopters operating at speeds of 90 MPH (145 Km/Hr) and more. The smaller AU 7000 sprayer (or equivalent) is recommended for use at airspeeds below 90 MPH. After spraying, the hydrocarbons can be rinsed off the shore rocks as described above with hand held pumps, deluge headers or boat spraying.
Vehicular Spraying - The recommended vehicular spraying is 50 to 150 ft2/gallon depending on climatic conditions. A MicroNair vehicle-mounted sprayer is recommended. This unit is a self contained sprayer kit that combines the AU 8000 sprayhead (or equivalent) with a powerful 4-stroke engine and a 60 liter chemical tank to give complete product coverage. After spraying, the hydrocarbons can then be rinsed off the shore rocks as described above with hand held pumps, deluge headers or boat spraying.
2. Concentration/Application Rate:
The product comes already mixed, and ready for use. For specific application, see rate of application as indicated above.
3. Conditions for Use:
Water temperature and salinity do not effect the product performance. PES-51 is effective against hydrocarbons only, and the age of the hydrocarbon is not relevant.

VII. TOXICITY AND EFFECTIVENESS

a. Toxicity:

Material Tested	Species	LC50 (ppm)
PES-51	Menidia beryllina Mysidopsis bahia	137.00 96-hr 54.00 48-hr
No. 2 Fuel Oil	Menidia beryllina Mysidopsis bahia	200.00 96-hr 11.50 48-hr
PES-51 & No. 2 Fuel Oil (1:10)	Menidia beryllina Mysidopsis bahia	435.00 96-hr 14.50 48-hr
Reference Toxicant (DSS)	Menidia beryllina Mysidopsis bahia	2.20 96-hr 9.80 48-hr

NOTE: This toxicity data was derived using the concentrated product. See Section VI of this bulletin for information regarding the manufacturer's recommendations for concentrations and application rates for field use.

b. Effectiveness:
NA

VIII. MICROBIOLOGICAL ANALYSIS
NA

IX. PHYSICAL PROPERTIES
1. Flash Point: 124ºF 2. Pour Point: -50ºF at 30 min. 3. Viscosity: 30 cst at 28ºC 4. Specific Gravity: 0.840 at 25ºC 5. pH: 6.7 6. Chemical Name and Percentage by Weight of the Total Formulation: CONFIDENTIAL 7. Surface Active Agents: CONFIDENTIAL 8. Solvents: CONFIDENTIAL 9. Additives: CONFIDENTIAL 10. Solubility: NA

X. ANALYSIS FOR HEAVY METALS, CYANIDE, AND CHLORINATED HYDROCARBONS

Compound	Concentration (ppm)
Arsenic	< 0.005
Cadmium	< 0.01
Chromium	< 0.05
Copper	< 0.05
Lead	< 0.05
Mercury	< 0.005
Nickel	< 0.01
Zinc	< 0.05
Cyanide	< 1.00
Chlorinated Hydrocarbons	< 0.01

PES-51

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